2024
(232) “Scaffold-Oriented Asymmetric Catalysis: Conformational Modulation of Transition State Multivalency during a Catalyst-Controlled Assembly of a Pharmaceutically Relevant Atropisomer”
Tampellini, N.; Mercado, B. Q.; Miller, S. J.
Chem Eur. J. 2024, 30, In Press. abstract
(231) “Enantioselective Sulfonimidamide Acylation via Cinchona Alkaloid-Catalyzed Desymmetrization; Scope, Data Science, and Mechanistic Investigation”
Hass, B. C.; Lim, N.-K.; Jermaks, J.; Gaster, E.; Guo, M. C.; Malig, T. C.; Werth, J.; Zhnag, H.; Toste, F. D.; Gosselin, F.; Miller, S. J.; Sigman, M. S.
J. Am. Chem. Soc. 2024, 146, In Press. abstract
2023
(230) Editorial: “Introduction: Remote and Late Stage Functionalization”
Miller, S. J.; Ritter, T.
Chem. Rev. 2023, 123, 13867-13868. abstract
(229) “Asymmetric Aromatic Finkelstein Reaction: A Peptide Catalysis Platform for Diarylmethine Desymmetrization”
Morack, T.; Myers, T. E.; Karas, L. J.; Hardy, M. A.; Mercado, B. Q.; Sigman, M. S.; Miller, S. J.
J. Am. Chem. Soc. 2023, 145, In Press. abstract
(228) “Data Science-Enabled Palladium-Catalyzed Enantioselective Aryl-Carbonylation of Sulfonimidamides”
Van Dijk, L.; Haas, B. C.; Lim, N.-K.; Clagg, K.; Dotson, J. J.; Treacy, S. M.; Piechowicz, K. A.; Roytman, V. A.; Zhang, H.; Toste, F. D.; Miller, S. J.; Gosselin, F.; Sigman, M. S.
J. Am. Chem. Soc. 2023, 145, 20959-20967. abstract
(227) “On the Ability of the N-O bond to Support a Stable Stereogenic Axis: Peptide-Catalyzed Atroposelective N-Oxidation”
Huth, S. E.; Stone, E. A.; Crotti, S.; Miller, S. J.
J. Org. Chem. 2023, 88, 12857-12862. abstract
(226) “Catalytic Asymmetric Hydrogen Atom Transfer: Enantioselective Hydroamination of Alkenes”
Henja, B. G.; Ganley, J. M.; Shao, H.; Tian, H.; Ellefsen, J. D.; Fastuca, N. J.; Houk, K. N.; Miller, S. J.; Knowles, R. R.
J. Am. Chem. Soc. 2023, 145, 16118-16129. abstract
(225) “Aspartyl β-Turn-Based Dirhodium(II) Metallopeptides for Benzylic C(sp3)-H Amination: Enantioselectivity and X-Ray Structural Analysis”
Van Den Heuvel, N.; Mason, S. M.; Mercado, B. Q.; Miller, S. J.
J. Am. Chem. Soc. 2023, 145, 12377-12385. abstract
(224) “Generality-Oriented Optimization of Enantioselective Aminoxyl Radical Catalysis”
Rein, J.; Rozema, S. D.; Langner, O. C.; Zacate, S. B.; Hardy, M. A.; Siu, J. C.; Mercado, B. Q.; Sigman, M. S.; Miller, S. J.; Lin, S.
Science 2023, 380, 706-712. abstract
(223) “Atomistic Simulations of the E. coli Ribosome Provide Selection Criteria for Translationally Active Substrates”
Watson, Z. L.; Knudson, I.; Ward, F. R.; Miller, S. J.; Cate, J. H. D.; Schepartz, A.; Abramyan, A. M.
Nature Chem. 2023, 15, 913-921. abstract
(222) “High-throughput Determination of Enantiopurity in Atroposelective Synthesis of Aryl Triazoles”
Lim, J.; Guo, M. C.; Choi, S.; Miller, S. J.; Anslyn, E. V.
Chem. Sci. 2023, 14, 5992-5999. abstract
(221) “Catalytic Asymmetric Synthesis of Atropisomeric N-Aryl 1,2,4-Triazoles”
Choi, S.; Guo, M. C.; Coombs, G. C.; Miller, S. J.
J. Org. Chem. 2023, 88, 7815-7820. abstract
(220) Editorial: “New Guidelines for Presenting Electrochemical Data in All ACS Journals”
Minteer, S.; Chen, J.; Lin, S.; Dehen, S.; Kamat, P. V.; Kozlowski, M. C.; Masson, G. M.; Miller, S. J.
J. Org. Chem. 2023, 88, 4036-4037.
Co-Published with ACS Catalysis, Org. Lett., Inorganic Chemistry, Organometallics, ACS Energy Lett. and ACS Au Journals. abstract
(219) Editorial: “Atropisomers: Synthesis, Analysis and Applications”
Kozlowski, M. C.; Miller, S. J.; Perreault, S.
Acc. Chem. Res. 2023, 56, 187-188. abstract
2022
(218) “Asymmetric Photochemical [2+2]-Cycloaddition of Acyclic Vinylpridines through Ternary Complex Formation and Uncontrolled Sensitization Mechanism”
Girvin, Z. C.; Cotter, L. F.; Yoon, H.; Chapman, S. J.; Mayer, J. M.; Yoon, T. P.; Miller, S. J.
J. Am. Chem. Soc. 2022, 144, 20109-20117. abstract
(217) Editorial: “Data Availability Statements in The Journal of Organic Chemistry, Organic Letters, and ACS Organic & Inorganic Au”
Masson, G.; Kozlowski, M. C.; Miller, S. J.
J. Org. Chem. 2022, 87, 12507-12509. abstract
Co-Published with Org. Lett. and ACS Organic & Inorganic Au.
(216) “Photocatalytic Reductive Olefin Hydrodifluoroalkylation Enabled by Tertiary Amine Reductants Compatible with Complex Systems”
Ellefsen, J. D.; Miller, S. J.
J. Org. Chem. 2022, 87, 10250-10255. abstract
(215) “Chemoselective Acylation of Nucleosides”
Tang, Y.; Grange, R. L.; Engl, O. D.; Miller, S. J.
Chem. Eur. J. 2022, 28, e202201661. abstract
(214) “Atroposelective Desymmetrization of Resorcinol-Bearing Quinazolines via Cu-Catalyzed C-O Bond Formation”
Yoon, H.; Galls, A.; Rozema, S. D.; Miller, S. J.
Org. Lett. 2022, 24, 762-766. abstract
2021
(213) “Kinetic Analysis of a Cysteine-Derived Thiyl-Catalyzed Asymmetric Vinylcyclopropane Cycloaddition Reflects Numerous Attractive Noncovalent Interactions”
Turek, A. K.; Sak, M. H.; Miller, S. J.
J. Am. Chem. Soc. 2021, 143, 16173-16183. abstract
(212) “Chirality-Matched Catalyst-Controlled Macrocyclization Reactions”
Hwang, J.; Mercado, B. Q.; Miller, S. J.
PNAS 2021, 118, e2113122118. abstract
(211) “Tunable and Cooperative Catalysis for Enantioselective Pictet-Spengler Reaction with Varied Nitrogen-Containing Heterocyclic Carboxaldehydes”
Chan, Y.-C.; Sak, M. H.; Frank, S. A.; Miller, S. J.
Angew. Chem. Int. Ed. 2021, 60, 24573-24581. abstract
(210) “Optimization of Triarylpyridinone Inhibitors of the Main Protease of SARS-CoV-2 to Low-Nanomolar Antiviral Potency”
Zhang, C.-H.; Spasov, K. A.; Reilly, R. R.; Hollander, K.; Stone, E. A.; Ippolito, J. A.; Liosi, M.-E.; Deshmukh, M. G.; Tirado-Rives, J.; Zhang, S.; Liang, Z.; Miller, S. J.; Isaacs, F.; Lindenbach, B. E.; Anderson, K. S.; Jorgensen, W. L.
ACS Med. Chem. Lett. 2021, 12, 1325-1332. abstract
(209) “Catalytic Enantioselective Synthesis of Pyridyl Sulfoximines”
Tang, Y.; Miller, S. J.
J. Am. Chem. Soc. 2021, 143, 9230-9235. abstract
(208) Editorial: “Green Chemistry: A Framework for a Sustainable Future”
Ganesh, K. N.; Zhand, D.; Miller, S. J.; Rossen, K.; Chirik, P. J.; Kozlowski, M. C.; Zimmerman, J. B.; Brooks, B. W.; Savage, P. E.; Allen, D. T.; Voutchkova-Kostal, A. M.
J. Org. Chem. 2021, 86, 8551-8555. abstract
Co-Published with several other journals and Editors-in-Chief of ACS Publications.
(207) “Structure-Guided Design of a Perampanel-Derived Pharmacophore Targeting the SARS-CoV-2 Main Protease”
Deshmukh, M. G.; Ippolito, J. A., Zhang, C.-H.; Stone, E. A., Reilly, R.; Miller, S. J.; Jorgensen, W. L.; Anderson, K. S.
Structure 2021, 29, 823-833. abstract
(206) “Isolating Conformers to Assess Dynamics of Peptidic Catalysts Using Computationally Designed Macrocyclic Peptides”
Stone, E. A.; Hosseinzadeh, P.; Craven, T. W.; Robertson, M. J.; Han, Y.; Hsieh, S.-Y.; Metrano, A. J.; Baker, D.; Miller, S. J.
ACS Catalysis 2021, 11, 4395-4400. abstract
(205) “Potent Noncovalent Inhibitors of the Main Protease of SARS-CoV‑2 from Molecular Sculpting of the Drug Perampanel Guided by Free Energy Perturbation Calculations”
Zhang, C.-H.; Stone, E. A.; Deshmukh, M.; Ippolito, J. A.; Ghahremanpour, M. M.; Tirado-Rives, J.; Spasov, K. A.; Zhang, S.; Takeo, Y.; Kudalkar, S. N.; Liang, Z.; Isaacs, F.; Lindenbach, B.; Miller, S. J.; Anderson, K. S.; Jorgensen, W. L.
ACS Cent. Sci. 2021, 7, 467-475. abstract
(204) “Catalytic Asymmetric and Stereodivergent Oligonucleotide Synthesis”
Featherston, A. L.; Kwon, Y.; Pompeo, M. M.; Engl, O. D.; Leahy, D. K.; Miller, S. J.
Science 2021, 371, 702-707. abstract
2020
(203) Editorial: “The Journal of Organic Chemistry: 85 Years in the Books”
Miller, S. J.
J. Org. Chem. 2020, 85, 15767-15769. abstract
(202) “Asymmetric Catalysis Mediated by Synthetic Peptides, Version 2.0: Expansion of Scope and Mechanisms”
Metrano, A. J.; Shugrue, C. R.; Kim, B.; Chinn, A. J.; Stone, E. A.; Miller, S. J.
Chem. Rev. 2020, 120, 11479-11615. abstract
(201) “Catalytic Dynamic Kinetic Resolutions in Tandem to Construct Two-Axis Terphenyl Atropisomers”
Beleh, O. M.; Miller, E.; Toste, F. D.; Miller, S. J.
J. Am. Chem. Soc. 2020, 142, 16461-16470. abstract
(200) “Asymmetric Catalysis Upon Helically Chiral Loratadine Analogs Unveils Enantiomer-Dependent Antihistamine Activity”
Stone, E. R.; Cutrona, K. J.; Miller, S. J.
J. Am. Chem. Soc. 2020, 142, 12690-12698. abstract
(199) Editorial: “Actions at J. Org. Chem., Org. Lett., and Organometallics to Combat Discrimination and Bias”
Carreira, E. M.; Chirik, P. J.; Miller, S. J.
J. Org. Chem. 2020, 85, 10285-10286. abstract
(198) “Application of High-Throughput Competition Experiments in the Development of Aspartate Directed Site-Selective Modification of Tyrosine Residues in Peptides”
Chinn, A. J.; Hwang, J.; Kim, B.; Parish, C. A.; Krska, S. W.; Miller, S. J.
J. Org. Chem. 2020, 85, 9424-9433. abstract
(197) Editorial: “Confronting Racism in Chemistry Journals”
Burrows, C. J. et al., including Miller, S. J.
J. Org. Chem. 2020, 85, 8297-8299. abstract
Co-Published with all journals and Editors-in-Chief of ACS Publications
(196) Editorial: “Update to Our Reader, Reviewer and Author Communities”
Burrows, C. J. et al., including Miller, S. J.
J. Org. Chem. 2020, 85, 5751-5752. abstract
Co-Published with all journals and Editors-in-Chief of ACS Publications
(195) “Catalysis-Enabled Access to Cryptic Geldanamycin Oxides”
Hilton, M. J.; Brackett, C. M.; Mercado, B. Q.; Blagg, B. S. J.; Miller, S. J.
ACS Cent Sci. 2020, 6, 426-435. abstract
(194) Editorial: “Encouraging Submission of FAIR Data at The Journal of Organic Chemistry and Organic Letters”
Hunter, A. M.; Carreira, E. M.; Miller, S. J.
J. Org. Chem. 2020, 85, 1773-1774. abstract
Co-Published with Org. Lett.
(193) Editorial: “From Russia, With Chemistry”
Carreira, E. M.; Nenajdenko, V. G.; Miller, S. J.; Chirik, P. J.; Meyer, K.
J. Org. Chem. 2020, 85, 1325-1327. abstract
Co-Published with Org. Lett. and Organometallics
(192) “Peptide-Catalyzed Fragment Couplings that Form Axially Chiral Non-C2-Symmetric Biaryls”
Coombs, G; Sak, M. H.; Miller, S. J.;
Angew. Chem. Int. Ed. 2020, 59, 2875-2880. abstract
(191) “Catalytic Sulfamoylation of Alcohols with Activated Aryl Sulfamates”
Rapp, P. B.; Murai, K.; Ichiishi, N.; Leahy, D. K.; Miller, S. J.
Org. Lett. 2020, 22, 168-174. abstract
(190) “Co(III)-Catalyzed C-H Amidation of Dehydroalanine for the Site-Selective Structural Diversification of Thiostrepton”
Scamp, R. J.; deRamon, E.; Paulson, E. K.; Miller, S. J.; Ellman, J. A.
Angew. Chem. Int. Ed. 2020, 59, 890-895. abstract
(189) “Site-Selective Nitrene Transfer to Conjugated Olefins Directed by Oxazoline Peptide Ligands”
Storch, G.; van den Heuvel, N.; Miller, S. J.
Adv. Synth. Catal. 2020, 362, 289-294. abstract
2019
(188) “Catalytic Enantioselective Pyridine N-Oxidation”
Hsieh, S.-Y.; Tang, Y.; Crotti, S.; Stone, E. A.; Miller, S. J.
J. Am. Chem. Soc. 2019, 141, 18624-18629. abstract
(187) “Reenginering a Reversible-Covalent Bonding Assembly to Optically Detect ee in b-Chiral Primary Alcohols”
Minus, M. B.; Featherston, A. L.; Choi, S.; King, S. C.; Miller, S. J.; Anslyn, E. V.
Chem 2019, 5, 3196-3206. abstract
(186) “Light-Driven Deracemization Enabled by Excited-State Electron Transfer”
Shin, N. Y.; Ryss, J. M.; Zhang, X.; Miller, S. J.; Knowles, R. R.
Science 2019, 366, 364-369. abstract
(185) “Site-Selective Acylation of Natural Products with BINOL-Derived Phosphoric Acids”
Li, J.; Grosslight, S.; Miller, S. J.; Sigman, M. S.; Toste, F. D.
ACS Catalysis 2019, 9, 9794-9799. abstract
(184) “Palladium-Catalyzed Suzuki-Miyaura Reactions of Aspartic Acid Derived Phenyl Esters”
Dardir, A. H.; Hazari, N.; Miller, S. J.; Shugrue, C. R.
Org. Lett. 2019, 21, 5762-5766. abstract
(183) “Translation of Diverse Aramid- and 1,3-Dicaronyl-Peptides by Wild Type Ribosomes in Vitro”
Ad, O.; Hoffman, K. S.; Cairns, A. G.; Featherston, A. L.; Miller, S. J.; Söll, D.; Schepartz, A.
ACS Cent. Sci. 2019, 5, 1289-1294. abstract
(182) Editorial: “The Journal of Organic Chemistry Global Enterprise”
Miller, S. J.
J. Org. Chem. 2019, 84, 4953. abstract
(181) “Terahertz Spectroscopy of Tetrameric Peptides”
Neu, J.; Stone, E. A.; Spies, J.; Storch, G.; Hatano, A. S.; Mercado, B. Q.; Miller, S. J.; Schmuttenmaer, C. A.
J. Phys. Chem. Lett. 2019, 10, 2624-2628. abstract
(180) “Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration”
Kwon, Y.; Li, J.; Reid, J. P.; Crawford, J. M.; Jacobs, R.; Sigman, M. S.; Toste, F. D.; Miller, S. J.
J. Am. Chem. Soc. 2019, 141, 6698-6705. abstract
(179) “Troponoid Atropisomers: Studies on the Configurational Stability of Tropone-Amide Chiral Axes”
Hirsch, D. R.; Metrano, A. J.; Stone, E. A.; Storch, G.; Miller, S. J.; Murelli, R. P.
Org. Lett. 2019, 21, 2412-2415. abstract
(178) “Structure and Reactivity of Highly Twisted N-Acyl Imidazoles”
Stone, E. A.; Mercado, B. Q.; Miller, S. J.
Org. Lett. 2019, 21, 2346-2351. abstract
(177) “Outer-Sphere Control for Divergent Multicatalysis with Common Catalytic Moieties”
Shugrue, C. R.; Sculimbrene, B. R.; Jarvo, E. R.; Mercado, B. Q.; Miller, S. J.
J. Org. Chem. 2019, 84, 199-215. abstract
(176) “Peptide-Based Catalysts Reach the Outer Sphere through Remote Desymmetrization and Atroposelectivity”
Metrano, A. J.; Miller, S. J.
Acc. Chem. Res. 2019, 52, 199-215. abstract
(175) “Phosphothreonine (pThr)–Based Multifunctional Peptide Catalysis for Asymmetric Baeyer Villiger Oxidations of Cyclobutanones”
Featherston, A. L.; Shugrue, C. R.; Mercado, B. Q.; Miller, S. J.
ACS Catalysis 2019, 9, 242-252. abstract
(174) “A Chemoselective Strategy for the Late Stage Functionalization of Complex Small Molecules with Polypeptides and Proteins through Selenocysteine”
Cohen, D. T.; Zhang, C.; Fadzen, C. M.; Mijalis, A. J.; Hie, L.; Johnson, K. D.; Shriver, Z.; Plante, O.; Miller, S. J.; Buchwald, S. L.; Pentelute, B. L.
Nature Chem. 2019, 11, 78-75. abstract
2018
(173) “A Stereodynamic Redox-Interconversion Network of Vicinal Tertiary and Quaternary Carbon Stereocenters in Hydroquinone Quinone Hybrid Dihydrobenzofurans”
Storch, G.; Kim, B.; Mercado, B. Q.; Miller, S. J.
Angew. Chem. Int. Ed. 2018, 57, 15107-15111. abstract
(172) “Molecular Dynamics Simulations of a Conformationally Mobile Peptide-Based Catalyst for Atroposelective Bromination”
Yan, X. C.; Metrano, A. J.; Robertson, M. J.; Abascal, N. C.; Tirado–Rives, J.; Miller, S. J.; Jorgensen, W. L.
ACS Catalysis 2018, 8, 9968-9979. abstract
(171) Editorial “Straddling the Rooftop: Finding a Balance Between Traditional and Modern Views of Chemistry”
Tolman, W. B.; Miller, S. J.; Chirik, P. J.; Smith III, A. B.
Co-Published: Inorg. Chem. 2018, 57, 11299-11305; Org. Lett. 2018, 20, 5075-5081; Organometallics 2018, 37, 2825-2831; J. Org. Chem. 2018, 83, 9573-9579. abstract
(170) “Divergent Control of Point and Axial Stereogenicity: Catalytic Enantioselective C−N Bond‐Forming Cross‐Coupling and Catalyst‐Controlled Atroposelective Cyclodehydration”
Kwon, Y.; Chinn, A.; Kim, B.; Miller, S. J.
Angew. Chem. Int. Ed. 2018, 57, 6251-6255. abstract
(169) “Rapid Phenolic O-Glycosylation of Small Molecules and Complex Unprotected Peptides in Aqueous Solvent”
Wadzinski, T. J.; Steinaur, A.; Hie, L.; Pelletier, G.; Schepartz, A.; Miller, S. J.
Nature Chem. 2018, 10, 644-652. abstract
(168) “Divergent Stereoselectivity in Phosphothreonine (pThr)-Catalyzed Reductive Aminations of 3-Amidocyclohexanones”
Shugrue, C. R.; Featherston, A. L.; Lackner, R. M.; Lin, A.; Miller, S. J.
J. Org. Chem. 2018, 83, 4491-4504. abstract
(167) “Disulfide-Bridged Peptides that Mediate Enantioselective Cycloadditions through Thiyl Radical Catalysis”
Ryss, J. M.; Turek, A. K.; Miller, S. J.
Org. Lett. 2018, 20, 1621-1625. abstract
(166) “Parameterization and Analysis of Peptide-Based Catalysts for the Atroposelective Bromination of 3-Arylquinazolin-4(3H)-ones”
Crawford, J. M.; Stone, E. A.; Metrano, A. J.; Miller, S. J.; Sigman, M. S.
J. Am. Chem. Soc. 2018, 140, 868-871. abstract
2017
(165) “Enantioselective Intermolecular C–O Bond Formation in the Desymmetrization of Diarylmethines Employing a Guanidinylated Peptide-Based Catalyst”
Chinn, A. J.; Kim, B.; Kwon, Y.; Miller, S. J.
J. Am. Chem. Soc. 2017, 139, 18107-18114. abstract
(164) “Desymmetrization of Diarylmethylamido Bis(phenols) through Peptide-Catalyzed Bromination: Enantiodivergence as a Consequence of a 2 amu Alteration at an Achiral Residue within the Catalyst”
Hurtley, A. E.; Stone, E. A.; Metrano, A. J.; Miller, S. J.
J. Org. Chem. 2017, 82, 11326-11336. abstract
(163) “Site- and Stereoselective Chemical Editing of Thiostrepton by Rh-Catalyzed Conjugate Arylation: New Analogs and Collateral Enantioselective Synthesis of Amino Acids”
Key, H. M.; Miller, S. J.
J. Am. Chem. Soc. 2017, 139, 15460-15466. abstract
(162) “Stereodynamic Quinone-Hydroquinone Molecules that Enantiomerize at sp3-Carbon via Redox-Interconversion”
Kim, B.; Storch, G. T.; Banerjee, G.; Mercado, B. Q.; Castillo-Lora, J.; Brudvig, G. W.; Mayer, J. M.; Miller, S. J.
J. Am. Chem. Soc. 2017, 139, 15239-15244. abstract
(161) “Identification and Partial Structural Characterization of Mass Isolated Valsartan and its Metabolite with Messenger Tagging Vibrational Spectroscopy”
Gorlova, O.; Colvin, S. M.; Brathwaite, A.; Menges, F. S.; Craig, S. M.; Miller, S. J.; Johnson, M. J.
J. Am. Soc. Mass Spectrom. 2017, 28, 2414-2422. abstract
(160) Review: “Applications of Non-Enzymatic Catalysts to the Alteration of Natural Products”
Shugrue, C. R.; Miller, S. J.
Chem. Rev. 2017, 117, 11894-11951. abstract
(159) “Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis”
Toste, F. D.; Sigman, M. S.; Miller, S. J.
Acc. Chem. Res. 2017, 50, 609-615. abstract
(158) “A Bottom Up Approach Towards Artificial Oxygenases by Combining Iron Coordination Complexes and Peptides”
Cussó, O.; Giuliano, M. W.; Ribas, X.; Miller, S. J.; Costas, M.
Chem. Sci. 2017, 8, 3660-3667. abstract
(157) “Diversity of Secondary Structure in Catalytic Peptides with Beta-Turn-Biased Sequences”
Metrano, A. J.; Abascal, N. C.; Mercado, B. Q.; Paulson, E. K.; Hurtley, A. E.; Miller, S. J.
J. Am. Chem. Soc. 2017, 139, 492-516. abstract
(156) Editorial: “Issue 1”
Miller, S. J.
J. Org. Chem. 2017, 82, 1-3. abstract
2016
(155) “Aspartyl Oxidation Catalysts that Dial In Functional Group Selectivity, along with Regio- and Stereoselectivity”
Alford, J. S.; Abascal, N. C.; Shugrue, C. R.; Colvin, S. M.; Romney, D. K.; Miller, S. J.
ACS Central Science 2016, 2, 733-739. abstract
(154) “Solution Structures and Molecular Associations of a Peptide-Based Catalyst for the Stereoselective Baeyer-Villiger Oxidation”
Abascal, N. C.; Miller, S. J.
Org. Lett. 2016, 18, 4646-4649. abstract
(153) Review: “Bifunctional Catalysis with Lewis Base Containing X-H Sites that Facilitate Proton Transfer or Hydrogen Bonding”
Mbofana, C. T.; Miller, S. J. in: Lewis Base Catalysis in Organic Synthesis, 2016, Vedejs, E.; Denmark, S. E. (Eds.); pp. 1259-1288.
Wiley-VCH Verlag GmbH & Co. KGaA. abstract
(152) “Synthesis and Evaluation of Phenylalanine-derived Trifluoromethyl Ketones for Peptide-based Oxidation Catalysis”
Featherston, A. L.; Miller, S. J.
Bioorg. Med. Chem. 2016, 24, 4871-4874. abstract
(151) “D-3-deoxy-dioctanoylphosphatidylinositol Induces Cytotoxicity in Human MCF-7 Breast Cancer Cells via a Mechanism that Involves Downregulation of the D-type Cyclin-Retinoblastoma Pathway”
Gradziel, C. S.; Jordan, P. A.; Jewel, D.; B.S.; Dufort, F. J.; Miller, S. J.; Chiles, T. C.; Roberts, M. F.
BBA – Mol. Cell Biol. L. 2016, 1861, 1808-1815. abstract
(150) “Distal Stereocontrol Using Guanidinylated Peptides as Multifunctional Ligands: Desymmetrization of Diarylmethanes via Ullman Cross-Coupling”
Kim, B.; Chinn, A. J.; Fandrick, D. R.; Senanayake, C. H.; Singer, R. A.; Miller, S. J.
J. Am. Chem. Soc. 2016, 138, 7939-7945. abstract
(149) “Structural Studies of β-Turn-Containing Peptide Catalysts for Atroposelective Quinazolinone Bromination”
Metrano, A. J.; Abascal. N. C.; Mercado, B. Q.; Paulson, E. K., Miller, S. J.
Chem. Commun. 2016, 52, 4816-4819. abstract
(148) “Aqueous Glycosylation of Unprotected Sucrose Employing Glycosyl Fluorides in the Presence of Calcium Ion and Trimethylamine”
Pelletier, G.; Zwicker, A.; Allen, C. L.; Schepartz, A.; Miller, S. J.
J. Am. Chem. Soc. 2016, 138, 3175-3182. abstract
(147) “A Stepwise Dechlorination/Cross-Coupling Strategy to Diversify the Vancomycin “In-Chloride”
Wadzinski, T. J.; Gea, K. D.; Miller, S. J.
Bioorg. Med. Chem. Lett. 2016, 26, 1025-1028. abstract
(146) “From Substituent Effects to Applications: Enhancing the Optical response of a Four-Component Assembly for Reporting EE Values”
Lin, C.-Y.; Giuliano, M. W.; Miller, S. J.; Anslyn, E. V.
Chem. Sci. 2016, 7, 4085-4090. abstract
(145) “Dual Genetic Encoding of Acetyl-lysine and Non-deacetylatable Thioacetyl-lysine Mediated by Flexizyme”
Xiong, H.; Reynolds, N. M.; Fan, C.; Englert, M.; Hoyer, D.; Miller, S. J.; Söll, D.
Angew. Chem. Int. Ed. 2016, 55, 4083-4086. abstract
(144) Review: “Site-Selective Reactions with Peptide-Based Catalysts”
Giuliano, M. W.; Miller, S. J.
Top. Curr. Chem. 2016, 372, 157-201. abstract
2015
(143) “Enantioselective Synthesis of 3-Arylquinazolin-4(3H)-ones via Peptide-Catalyzed Atroposelective Bromination”
Diener, M. E.; Metrano, A. J.; Kusano, S.; Miller, S. J.
J. Am. Chem. Soc. 2015, 137, 12369-12377. abstract
(142) “Improved Carbohydrate Recognition in Water with an Electrostatically Enhanced β-Peptide Bundle”
Melicher, M. S.; Walker, A. S.; Shen, J.; Miller, S. J.; Schepartz, A.
Org. Lett. 2015, 17, 4718-4721. abstract
(141) “Phosphothreonine as a Catalytic Residue in Peptide-Mediated Asymmetric Transfer Hydrogenations of 8-Aminoquinolines”
Shugrue, C. R.; Miller, S. J.
Angew. Chem. Int. Ed. 2015, 54, 11173-11176. abstract
(140) “A Synergistic Combinatorial and Chiroptical Study of Peptide Catalysts for Asymmetric Baeyer–Villiger Oxidation”
Giuliano, M. W.; Lin, C.-Y.; Romney, D. K.; Miller, S. J.; Anslyn, E. V.
Adv. Synth. Catal. 2015, 357, 2301-2309. abstract
(139) Perspective: “Climbing Jacob’s Ladder – Protein Design Enables the Stabilization of a Transient Molecular State”
Romney, D. K.; Miller, S. J.
Science 2015, 347, 829. abstract
(138) “Structure Diversification of Vancomycin through Peptide-Catalyzed, Site-Selective Lipidation: A Catalysis-Based Approach to Combat Glycopeptide-Resistant Pathogens”
Yoganathan, S.; Miller, S. J.
J. Med. Chem. 2015, 58, 2367-2377. abstract
(137) “Regioselective Derivatizations of a Tribrominated Atropisomeric Benzamide Scaffold”
Barrett, K. T.; Miller, S. J.
Org. Lett. 2015, 17, 580-583. abstract
(136) “Multivalency as a Key Factor for High Activity of Selective Supported Organocatalysts for the Baylis-Hillman Reaction”
Goren, K.; Karabline, J.; Shiloni, Y.; Barak, E.; Miller, S. J.; Portnoy, M.
Chem. Eur. J. 2015, 22, 1191-1197. abstract
2014
(135) “Catalyst Control over Regio- and Enantioselectivity in Baeyer-Villiger Oxidations of Functionalized Ketones”
Romney, D. K.; Colvin, S. M.; Miller, S. J.
J. Am. Chem. Soc. 2014, 136, 14019-14022. abstract
(134) “Phosphine-Catalyzed Annulation Reactions of 2-Butynoate and a-Keto Esters: Synthesis of Cyclopentene Derivatives”
Mbofana, C. T.; Miller, S. J.
ACS Catalysis 2014, 4, 3671-3674. abstract
(133) “X-ray Crystal Structure of Teicoplanin A2-2 Bound to a Catalytic Peptide Sequence via the Carrier Protein Strategy”
Han, S.; Le, B.V.; Hajare, H. S.; Baxter, R. H. G.; Miller, S. J.
J. Org. Chem. 2014, 79, 8550-8556. abstract
(132) “Function-Oriented Investigations of a Peptide-Based Catalyst that Mediates Enantioselective Allylic Alcohol Epoxidation”
Abascal, N. C.; Lichtor, P. A.; Giuliano, M. W. Miller, S. J.
Chem. Sci. 2014, 5, 4504-4511. abstract
(131) “Total Synthesis and Isolation of Citrinalin and Cyclopiamine Congeners”
Mercado-Marin, E. V.; Garcia-Reynaga, P.; Romminger, S.; Pimenta, E. F.; Romney, D. K.; Lodewyk, M. W.; Williams, D. E.; Andersen, R. J.; Miller, S. J.; Tantillo, D. J.; Berlinck, R. G. S.; Sarpong, R.
Nature, 2014, 509, 318-324. abstract
(130) “Spontaneous Transfer of Chirality in an Atropisomerically Enriched Two-Axis System”
Barrett, K. T.; Metrano, A. J.; Rablen, P. R.; Miller, S. J.
Nature 2014, 509, 71-75. abstract
(129) “Experimental Lineage and Functional Analysis of a Remotely Directed Peptide Epoxidation Catalyst”
Lichtor, P. A.; Miller, S. J.
J. Am. Chem. Soc. 2014, 136, 5301-5308. abstract
(128) “Diastereo- and Enantioselective Addition of Anilide-Functionalized Allenoates to N-Acyl Imines Catalyzed by a Pyridylalanine-Based Peptide”
Mbofana, C. T.; Miller, S. J.
J. Am. Chem. Soc. 2014, 136, 3285-3292. abstract
(127) “Peptide-Catalyzed Conversion of Racemic Oxazol-5(4H)-ones into Enantiomerically Enriched α-Amino Acid Derivatives”
Metrano, A. J.; Miller, S. J.
J. Org. Chem. 2014, 79, 1542-1554. abstract
(126) “A Fully Synthetic and Biochemically Validated Phosphatidyl Inositol-3-Phosphate Hapten via Asymmetric Synthesis and Native Chemical Ligation”
Chandler, B. D.; Burkhardt, A. L.; Foley, K.; Cullis, C.; Driscoll, D.; Roy D’Amore, N.;
Miller, S. J.
J. Am. Chem. Soc. 2014, 136, 412-418. abstract
2013
(125) “Chiral Copper(II) Complex-Catalyzed Reactions of Partially Protected Carbohydrates”
Allen, C. L.; Miller, S. J.
Org Lett. 2013, 15, 6178-6181. abstract
(124) “Combined Lewis Acid and BrØnstead Acid-Mediated Reactivity of Glycosyl Trichloroacetimidate Donors”
Gould, N. D.; Allen, C. L.; Nam, B. C.; Schepartz, A.; Miller, S. J.
Carbohydr. Res. 2013, 382, 36-42. abstract
(123) “Asymmetric Catalysis at a Distance: Catalytic, Site-Selective Phosphorylation of Teicoplanin”
Han, S.; Miller, S. J.
J. Am. Chem. Soc. 2013, 135, 12414-12421. abstract
(122) “A β-Boronopeptide Bundle of Known Structure as a Vehicle for Polyol Recognition”
Melicher, M. S.; Chu, J.; Walker, A. S.; Miller, S. J.; Baxter, R. H. G.; Schepartz, A.
Org. Lett. 2013, 15, 5048-5051. abstract
(121) “An Efficient Chemical Synthesis of Carboxylate-Isostere Analogs of Daptomycin”
Yoganathan, S.; Yin, N.; He, Y.; Mesleh, M.; Gu, Y. G.; Miller, S. J.
Org. Biomol. Chem. 2013, 11, 4680-4685. abstract
(120) “Chemical Tailoring of Teicoplanin with Site-Selective Reactions”
Pathak, T. P.; Miller, S. J.
J. Am. Chem. Soc. 2013, 135, 8415-8422. abstract
(119) “The Roles of Counterion and Water in a Stereoselective Cysteine-Catalyzed Rauhut-Currier Reactions: A Challenge for Computational Chemistry”
Osuna, S.; Dermenci, A.; Miller, S. J.; Houk, K. N.
Chem. Eur. J. 2013, 19, 14245-14253. abstract
(118) “Enantioselective Synthesis of Atropisomeric Benzamides through Peptide-Catalyzed Bromination”
Barrett, K. T.; Miller, S. J.
J. Am. Chem. Soc. 2013, 135, 2963-2966. abstract
(117) “N-Methylimidazole-Catalyzed Synthesis of Carbamates from Hydroxamic Acids via the Lossen Rearrangement”
Yoganathan, S.; Miller, S. J.
Org. Lett. 2013, 15, 602-605. abstract
2012
(116) “Combinatorial Evolution of Site- and Enantioselective Catalysts for Polyene Epoxidation”
Lichtor, P. A.; Miller, S. J.
Nature Chem. 2012, 4, 990-995. abstract
(115) “Catalytic Site-Selective Thiocarbonylations and Deoxygenations of Vancomycin Reveal Hydroxyl-Dependent Conformational Effects”
Fowler, B. S.; Laemmerhold, K. M.; Miller, S. J.
J. Am. Chem. Soc. 2012, 134, 9755-9761. abstract
(114) “Correlating Sterics in Catalysis”
Miller, S. J.
Nature Chem. 2012, 4, 344-345. abstract
(113) “Site-Selective Bromination of Vancomycin”
Pathak, T. P.; Miller, S. J.
J. Am. Chem. Soc. 2012, 134, 6120-6123. abstract
(112) “An Approach to the Site-Selective Deoxygenation of Hydroxyl Groups Based on Catalytic Phosphoramidite Transfer”
Jordan, P. A.; Miller, S. J.
Angew. Chem. Int. Ed. 2012, 51, 2907-2911. abstract
(111) “A Peptide-Embedded Trifluoromethyl Ketone Catalyst for Enantioselective Epoxidation”
Romney, D. K.; Miller, S. J.
Org. Lett. 2012, 14, 1138-1141. abstract
(110) “Determination of Non-Covalent Docking by IR Spectroscopy of Cold Gas-Phase Complexes “
Garand, E.; Kamrath, M. Z.; Jordan, P. A.; Wolk, A. B.; McCoy, A. B.; Miller, S. J.;
Johnson, M. A.
Science 2012, 335, 694-698. abstract
(109) “Polymer-supported Enantioselective Bifunctional Catalysts for Nitro-Michael Addition of Ketones and Aldehydes”
Tuchman-Shukron, L.; Miller, S. J.; Portnoy, M.
Chem. Eur. J. 2012, 18, 2290-2296. abstract
2011
(108) “Chemo-Enzymatic Synthesis of Each Enantiomer of
Orthogonally-Protected 4,4-Difluoroglutamic Acid – A Candidate Monomer for
Chiral Brønsted-Acid Peptide-Based Catalysts”
Li, Y.; Miller, S. J.
J. Org. Chem. 2011, 76, 9785-9791. abstract
(107) “Divergent Reactivity in Amine- and Phosphine-Catalyzed C-C Bond Forming Reactions of Allenoates with 2,2,2-Trifluoroacetophenones”
Saunders, L. B.; Miller, S. J.
ACS Catalysis 2011, 1, 1347-1350. abstract
(106) “Quasi-Biomimetic Ring Contraction Catalyzed by a Cysteine-Based Nucleophile: Total Synthesis of Sch-642305, Some Analogs and their Putative anti-HIV Activities”
Dermenci, A.; Selig, P. S.; Domaoal, R. A.; Spasov, K. A.; Anderson, K. S.; Miller, S. J.
Chem. Sci. 2011, 2, 1568-1572. abstract
(105) “Chemoselective and Enantioselective Oxidation of Indoles Employing Aspartyl Peptide Catalysts”
Kolundzic, F.; Noshi, M. N.; Tjandra, M.; Movassaghi, M.; Miller, S. J.
J. Am. Chem. Soc. 2011, 133, 9104-9111. abstract
(104) “A One-Bead-One-Catalyst Approach to Aspartic Acid-Based Oxidation Catalyst Discovery” Lichtor, P. A.; Miller, S. J.
ACS Comb. Sci. 2011, 13, 321-326. abstract
(103) “Synthesis of Atropisomerically Defined, Highly Substituted Biaryl Scaffolds through Catalytic Enantioselective Bromination and Regioselective Cross-Coupling”
Gustafson, J. L.; Lim, D.; Barrett, K. T.; Miller, S. J.
Angew. Chem. Int. Ed. 2011, 50, 5125-5129. abstract
(102) “Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer Sphere Pathway”
Dobereiner, G. E.; Nova, A.; Schley, N. D.; Hazari, N.; Miller, S. J.; Eisenstein, O.;
Crabtree, R. H.
J. Am. Chem. Soc. 2011, 133, 7547-7562. abstract
(101) “Vibrational Characterization of Simple Peptides Using Cryogenic Infrared Photodissociation of H2-Tagged, Mass-Selected Ions”
Kamrath, M. Z.; Garand, E.; Jordan, P. A.; Leavitt, C. M.; Wolk, A. B.; Van Stipdonk, M. J.; Miller, S. J.; Johnson, M. A.
J. Am. Chem. Soc. 2011, 133, 6440-6448. abstract
(100) “Ortho-Acidic Aromatic Thiols as Efficient Catalysts of Intramolecular Morita-Baylis-Hillman and Rauhut-Currier Reactions”
Selig. P. S.; Miller, S. J.
Tetrahedron Lett. 2011, 52, 2148-2151. abstract
2010
(99) “Pyridylalanine (Pal)-Peptide Catalyzed Enantioselective Allenoate Additions to N-Acyl Imines Proceed via an Atypical “Aza-Morita-Baylis-Hillman” Mechanism”
Saunders, L. B.; Cowen, B. J.; Miller, S. J.
Org. Lett. 2010, 12, 4800-4803. abstract
(98) “Development of a Cysteine-Catalyzed Enantioselective Rauhut−Currier Reaction”
Aroyan, C. E.; Dermenci, A.; Miller, S. J.
J. Org. Chem. 2010, 75, 5784–5796. abstract
(97) “Linear Free Energy Relationship Analysis of a Catalytic Desymmetrization Reaction of a Diarylmethane-Bis(phenol)”
Gustafson, J.; Sigman, M. S.; Miller, S. J.
Org. Lett. 2010, 12, 2794-2797. abstract
(96) “Dynamic Kinetic Resolution of Biaryl Atropisomers via Peptide-Catalyzed Asymmetric Bromination”
Gustafson, J.; Lim, D.; Miller, S. J.
Science 2010, 328, 1251-1255. abstract
(95) “Asymmetric Phosphorylation through Catalytic P(III) Phosphoramidite Transfer: Enantioselective Total Synthesis of myo-Inositol-6-Phosphate”
Jordan, P. A.; Kayser-Bricker, K. J.; Miller, S. J.
Proc. Nat. Acad. Sci. U. S. A. 2010, 107, 20620-20624. abstract
(94) “n→π* Interaction and n)(π Pauli Repulsion Are Antagonistic for Protein Stability”
Jakobsche, C. E.; Choudhary, A.; Miller, S. J.; Raines, R. T.
J. Am. Chem. Soc. 2010, 132, 6651-6653. abstract
(93) “Peptide-Catalyzed Kinetic Resolution of Formamides and Thioformamides as an Entry to Nonracemic Amines”
Fowler, B. S.; Mikochik, P. J.; Miller, S. J.
J. Am. Chem. Soc. 2010, 132, 2870-2871. abstract
2009
(92) “Enantioselective Sulfonylation Reactions Mediated by a Tetrapeptide Catalyst”
Fiori, K. W.; Puchlopek, A. L. A.; Miller, S. J.
Nature Chem. 2009, 1, 630-634. abstract
(91) “An Approach to the Site-Selective Diversification of Apoptolidin A with Peptide-Based Catalysts”
Lewis, C. A.; Longcore, K. E.; Miller, S. J.; Wender, P. A.
J. Nat. Prod. 2009, 72, 1864-1869. abstract
See also: “Highlights”
Nature Chem. Biol. 2009, 5, 786. toc
(90) “Regio- and Stereoselective Synthesis of Fluoroalkenes by Directed Au(I)-Catalysis”
Gorske, B. C.; Mbofana, C. T.; Miller, S. J.
Org. Lett. 2009, 11, 4318-4321. abstract
(89) Review: “Enantioselective Catalysis and Complexity Generation from Allenoates”
Cowen, B. J.; Miller, S. J.
Chem. Soc. Rev. 2009, 38, 3102-3116. abstract
(88) Commentary: “Natural Products: Beyond Grind and Find”
Miller, S. J.; Clardy, J.
Nature Chem. 2009, 1, 261-263. abstract
(87) “Asymmetric Syntheses of L,L- and L,D-Di-myo-Inositol-1,1’-Phosphate
and their Behavior as Stabilizers of Enzyme Activity at Extreme
Temperatures”
Longo, C. M.; Wei, Y.; Roberts, M. F.; Miller, S. J.
Angew. Chem. Int. Ed. 2009, 48, 4158-4161. abstract
(86)”Pyridylalanine (Pal)-Peptide Catalyzed Enantioselective Allenoate Additions to N-Acyl Imines”
Cowen, B. J.; Saunders, L. B.; Miller, S. J.
J. Am. Chem. Soc. 2009, 131, 6105-6107. abstract
(85) “Disparate Behavior of Carbonyl and Thiocarbonyl Compounds: Acyl Chlorides vs Thiocarbonyl Chlorides and Isocyanates vs Isothiocyanates”
Wiberg, K. B.; Wang, Y.-G.; Miller, S. J.; Puchlopek, A. L. A.; Bailey, W. F.; Fair, J. D.
J. Org. Chem. 2009, 74, 3659-3664. abstract
(84) Commentary: “Total Chemical Synthesis Peers into the Biosynthetic Black Box”
Miller, S.J.
Science 2009, 324, 186-187. abstract
(83) Review: “The Rauhut-Currier Reaction: A History and Its Synthetic Application”
Aroyan, C. E.; Dermenci, A.; Miller, S. J.
Tetrahedron 2009, 65, 4069-4084. abstract
2008
(82) “A Case of Remote Asymmetric Induction in the Peptide-Catalyzed
Desymmetrization of a Bis(phenol)”
Lewis, C. A.; Gustafson, J. L.; Chiu, A.; Balsells, J.; Pollard, D.; Murry,
J.; Reamer, R. A.; Hansen, K. B.; Miller, S. J.
J. Am. Chem. Soc. 2008, 130, 16358-16365. abstract
(81) “Catalytic Site-Selective Synthesis and Evaluation of a Series of
Erythromycin Analogs”
Lewis, C. A.; Merkel, J.; Miller, S. J.
Bioorg. Med. Chem. Lett. 2008, 18, 6007-6011. abstract
(80) “Functional Analysis of an Aspartate-Based Epoxidation Catalyst with
Amide-to-Alkene Peptidomimetic Catalyst Analogues”
Jakobsche, C. E.; Peris, G.; Miller, S. J.
Angew. Chem. Int. Ed. 2008, 47, 6707-6711. abstract
(79) “A Nonenzymatic Acid/Peracid Catalytic Cycle for the Baeyer-Villiger
Oxidation”
Peris, G.; Miller, S. J.
Org. Lett. 2008, 10, 3049-3052. abstract
(78) Commentary: “Triumph of a Chemical Underdog”
Peris, G.; Miller, S. J.
Nature 2008, 452, 415-416. abstract
77) “Catalyst-Dependent Syntheses of Phosphatidylinositol-5-Phosphate-DiC8
and its Enantiomer”
Kayser-Bricker, K. J.; Jordan, P. A.; Miller, S. J.
Tetrahedron 2008, 64, 7015-7020. abstract
(76) “Insights into the Structural Specificity of the Cytotoxicity of
3-Deoxy-Phosphatidylinositols”
Wang, Y. K.; Chen, W.; Blair, D.; Pu, M.; Xu, Y.; Miller, S. J.; Redfield,
A. G.; Chiles, T. C.; Roberts, M. F.
J. Am. Chem. Soc. 2008, 130, 7746-7755. abstract
(75) “Selective Partial Reduction of Quinolines: Hydrosilylation versus
Transfer Hydrogenation”
Voutchkova, A. M.; Gnanamgari, D.; Jakobsche, C. E.; Butler, C.; Miller, S.J.; Parr, J.;
Crabtree, R. H.
J. Organomet. Chem. 2008, 693, 1815-1821. abstract
(74) “Site-Selective Catalysis of Phenyl Thionoformate Transfer as a Tool
for Regioselective Deoxygenation of Polyols”
Sánchez-Roselló, M.; Puchlopek, A. L. A.; Morgan, A. J.; Miller, S. J.
J. Org. Chem. 2008, 73, 1774-1782. abstract
2007
(73) “Asymmetric Catalysis Mediated by Synthetic Peptides”
Colby Davie, E.; Mennen, S. M.; Xu, Y.; Miller, S. J.
Chem. Rev. 2007, 107, 5759-5812. abstract
(72) “Enantioselective [3+2]-Cycloadditions Catalyzed by a Protected, Multifunctional Phosphine-Containing α-Amino Acid”
Cowen, B.J.; Miller, S.J.
J. Am. Chem. Soc. 2007, 129, 10988-10989. abstract
(71) “Aspartate-Catalyzed Asymmetric Epoxidation Reactions”
Peris, G.; Jakobsche, C. E.; Miller, S. J.
J. Am. Chem. Soc. 2007, 129, 8710-8711. abstract
(70) “Development of a Bio-Inspired Acyl-Anion Equivalent Macrocyclization
and Synthesis of a trans-Resorcylide Precursor”
Mennen, S. M.; Miller, S. J.
J. Org. Chem. 2007, 72, 5260-5269. abstract
(69) “Asymmetric Michael Addition of a-Nitro-Ketones Using Catalytic Peptides”
Linton, B. R.; Reutershan, M. H.; Aderman, C. M.; Richardson, E. A.;
Brownell, K. R.; Ashley, C. W.; Evans, C. A.; Miller, S. J.
Tetrahedron Lett. 2007, 48, 1993-1997. abstract
(68) “Enantioselective Rauhut-Currier Reactions Promoted By Protected Cysteine”
Aroyan, C. E.; Miller, S. J. J. Am. Chem. Soc. 2007, 129, 256-257. abstract
2006
(67) “Remote Desymmetrization at Near-Nanometer Group Separation Catalyzed by a Miniaturized Enzyme Mimic”
Lewis, C. A.; Chiu, A.; Kubryk, M.; Balsells, J.; Pollard, D.; Esser, C. K.; Murry, J.; Reamer, R. A.; Hansen, K. B.; Miller, S. J.
J. Am. Chem. Soc. 2006, 128, 16454-16455. abstract
See also: “Research Highlights” Nature 2006, 444, 974-975. abstract
(66) “Site-Selective Derivatization and Remodeling of Erythromycin A Using Peptide-Based Chiral Catalysts”
Lewis, C. A.; Miller, S. J.
Angew. Chem. Int. Ed. 2006, 45, 5616-5619. abstract
See also: “Editor’s Choice” Science 2006, 313, 592-593. abstract
(65) “Unified Total Syntheses of the Inositol Polyphosphates: D-I-3,5,6P3, D-I-3,4,5P3, D-I-3,4,6P3 and D-I-3,4,5,6P4 via Catalytic Enantioselective and Site-Selective Phosphorylation”
Morgan, A. J.; Komiya, S.; Xu, Y.; Miller, S. J.
J. Org. Chem. 2006, 71, 6923-6931. abstract
(64) “Amino Acid-Peptide-Catalyzed Enantioselective Baylis-Hillman Reactions”
Vasbinder, M. M.; Imbriglio, J. E.; Miller, S. J.
Tetrahedron 2006, 62, 11450-11459. abstract
(63) “Streamlined Synthesis of Phosphatidylinositol (PI), PI3P, PI3,5P2 and Deoxygenated Analogs as Potential Biological Probes”
Xu, Y.; Sculimbrene, B. R.; Miller, S. J.
J. Org. Chem. 2006, 71, 4919-4928. abstract
(62) “Dihedral Angle Restriction within a Peptide-Based Tertiary-Alcohol Kinetic Resolution Catalyst”
Angione, M. C.; Miller, S. J.
Tetrahedron 2006, 62, 5254-5261. abstract
(61) “Temperature Dependence of the Inositol Monophosphates. Km Correlates with Di-myo-Inositol-1,1’-Phosphate Accumulation in Archaeoglobus fulgidus”
Wang, Y. K.; Morgan, A. J.; Stieglitz, K.; Stec, B.; Thompson, B.; Miller, S. J.; Roberts, M. F.
Biochemistry 2006, 45, 3307-3314. abstract
(60) “Studies of Folded Peptide-Based Catalysts for Organic Synthesis”
Blank, J. T.; Miller, S. J.
Biopolymers (Pept. Sci.) 2006, 84, 38-47. abstract
2005
(59) “Dual Catalyst Control in the Enantioselective Intramolecular Morita-Baylis-Hillman Reaction”
Aroyan, C. E.; Vasbinder, M. M.; Miller, S. J.
Org. Lett. 2005, 7, 3849-3851. abstract
(58) “Desymmetrization of Glycerol Derivatives with Peptide-Based Acylation Catalysts”
Lewis, C. A.; Sculimbrene, B. R.; Xu, Y.; Miller, S. J.
Org. Lett. 2005, 7, 3021-3023. abstract
(57) “Peptide Bond Isosteres: Ester or (E)-Alkene in the Backbone of the Collagen Triple Helix”
Jenkins, C. L.; Vasbinder, M. M.; Miller, S. J.; Raines, R. T.
Org. Lett. 2005, 7, 2619-2622. abstract
(56) “Diversity-Generation from an Alleneoate-Enone Coupling: Syntheses of Azepines and Pyrimidones from Common Precursors”
Evans, C. A.; Cowen, B. J.; Miller, S. J.
Tetrahedron 2005, 61, 6309-6314.abstract
(55) “Thiazolylalanine-Derived Catalysts for Enantioselective Intermolecular Aldehyde-Imine Cross-Couplings”
Mennen, S. M.; Gipson, J. D.; Kim, Y. R.; Miller, S. J.
J. Am. Chem. Soc. 2005, 127, 1654-1655. abstract
(54) “A Peptide-Catalyzed Stetter Reaction”
Mennen, S. M.; Blank, J. T.; Tran-Dubé, M. B.; Imbriglio, J. E.; Miller, S. J.
Chem. Commun. 2005, 195-197.
Designated a “Hot Paper” by the Editors of Chem. Commun. abstract
(53) Review: “Enantioselective Synthesis of b-Amino Acids via Conjugate Addition to a,b-Unsaturated Carbonyl Compounds”
Miller, S. J.; Guerin, D. J. in Enantioselective Synthesis of b-Amino Acids, E. Juaristi and V. Soloshonok, Eds. John Wiley & Sons, New Jersey, USA, 2005, Chapter 15, pp. 351-376.
(52) “Photolithographic Patterning of Ring-Opening Metathesis Catalysts on Silicon”
Harris, R. F.; Ricci, M. J.; Farrer, R. A.; Praino, J.; Miller, S. J.; Saleh, B. E.; Teich, M. C.; Fourkas, J. T.
Adv. Mat. 2005, 17, 39-42. abstract
2004
(51) “Chemistry and Biology of Deoxy-myo-Inositol Phosphates: Stereospecificity of Substrate Interactions within an Archaeal and a Bacterial IMPase”
Morgan, A. J.; Wang, Y. K.; Roberts, M. F.; Miller, S. J.
J. Am. Chem. Soc. 2004, 126, 15370-15371. abstract
(50) Commentary: “DNA as a Template for Reaction Discovery”
Miller, S. J.
Nature Biotechnology 2004, 22, 1378-1379. abstract
(49) “Asymmetric Syntheses of Phosphatidylinositol-3-Phosphates with Saturated and Unsaturated Side Chains through Catalytic Asymmetric Phosphorylation”
Sculimbrene, B. R.; Xu, Y.; Miller, S. J.
J. Am. Chem. Soc. 2004, 126, 13182-13183. abstract
(48) “Catalytic Enantioselective Synthesis of Sulfinate Esters Through the Dynamic Resolution of tert-Butanesulfinyl Chloride”
Evans, J. W.; Fierman, M. B.; Miller, S. J.; Ellman, J. A.
J. Am. Chem. Soc. 2004, 126, 8134-8135. abstract
(47) “Structure-Selectivity Relationships and Structure for a Peptide-Based Enantioselective Acylation Catalyst”
Fierman, M. B.; O’Leary, D. J.; Steinmetz, W. E.; Miller, S. J.
J. Am. Chem. Soc. 2004, 126, 6967-6971. abstract
(46) “In Search of Peptide-Based Catalysts for Asymmetric Organic Synthesis”
Miller, S. J.
Acc. Chem. Res. 2004, 37,601-610. abstract
(45) “Synthesis of Aziridinomitosenes through Base-Catalyzed Conjugate Addition”
Tsuboike, K.; Guerin, D. J.; Mennen, S. M.; Miller, S. J.
Tetrahedron 2004, 60, 7367-7374. abstract
(44) Review: “Acylation Reactions”
Jarvo, E. R.; Miller, S. J. in Comprehensive Asymmetric Catalysis Supplement 1, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds. Springer-Verlag, Berlin Heidelberg, 2004, Chapter 43, pp. 189-206.
2003
(43) “Amine-Catalyzed Coupling of Allenic Esters to a,b-Unsaturated Carbonyls”
Evans, C. A.; Miller, S. J.
J. Am. Chem. Soc. 2003, 125, 12394-12395. abstract
(42) “Dual Catalyst Control in the Amino Acid-Peptide-Catalyzed Enantioselective Baylis-Hillman Reaction”
Imbriglio, J. E.; Vasbinder, M. M.; Miller, S. J.
Org. Lett. 2003, 5, 3741-3743. abstract
See also: “The Many Faces of Combinatorial Chemistry”
Borman, S.
Chemical and Engineering News 2003, October 27, p. 52. abstract
(41) “Acyl Sulfonamide Catalysts for Glycosylation Reactions with Trichloroacetimidate Donors”
Griswold, K. S.; Horstmann, T. E.; Miller, S. J.
Synlett 2003, 1923-1926. abstract
(40) ”Nonenzymatic Peptide-Based Catalytic Asymmetric Phosphorylation of Inositol Derivatives”
Sculimbrene, B. R.; Morgan, A. J.; Miller, S. J.
Chem. Commun. 2003, 1781-1785. abstract
(39) “A Peptide-Based Catalyst Approach to the Regioselective Functionalization of Carbohydrates”
Griswold, K. S.; Miller, S. J.
Tetrahedron 2003, 59, 8869-8875. abstract
(38) Review: “Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis”
France, S.; Guerin, D. J.; Miller, S. J.; Lectka, T.
Chem. Rev. 2003, 103, 2985-3012. abstract
(37) “Enantioselective Synthesis of an Aziridinomitosane and Selective Functionalizations of a Key Intermediate”
Papaioannou, N.; Blank, J. T.; Miller, S. J.
J. Org. Chem. 2003, 68, 2728-2734. abstract
2002
(36) “Enantiodivergence in Small-Molecule Catalysis of Asymmetric Phosphorylation: Concise Total Syntheses of the Enantiomeric D-myo-Inositol-1-Phosphate and D-myo-Inositol-3-Phosphate”
Sculimbrene, B. R.; Morgan, A. J.; Miller, S. J.
J. Am. Chem. Soc. 2002, 124, 11653-11656. abstract
(35) “Synthesis of the Pro-Gly Dipeptide Alkene Isostere Using Olefin Cross Metathesis”
Vasbinder, M. M.; Miller, S. J.
J. Org. Chem. 2002, 67, 6240-6242. abstract
(34) “Asymmetric Azidation-Cycloaddition With Open-Chain Peptide-Based Catalysts. A Sequential Enantioselective Route to Triazoles”
Guerin, D. J.; Miller, S. J.
J. Am. Chem. Soc. 2002, 124, 2134-2136. abstract
(33) Review: “Proton-Activated Fluorescence as a Tool for Simultaneous Screening of Combinatorial Chemical Reactions”
Evans, C. A.; Miller, S. J.
Current Opinion in Chemical Biology 2002, 6, 333-338. abstract
(32) Review: “Amino Acids and Peptides as Asymmetric Organocatalysts”
Jarvo, E. R.; Miller, S. J.
Tetrahedron 2002, 58, 2481-2495. abstract
(31) “Production, Analysis, and Application of Spatially-Resolved Shells in Solid-Phase Polymer Spheres”
Farrer, R. A; Copeland, G. T.; Previte, M. J. R.; Okamoto, M. M.; Miller, S. J.; Fourkas, J. T.
J. Am. Chem. Soc. 2002, 124, 1994-2003. abstract
2001
(30) “Discovery of a Catalytic Asymmetric Phosphorylation through Selection of a Minimal Kinase Mimic: A Concise Total Synthesis of D-myo-Inositol-1-Phosphate”
Sculimbrene, B. R.; Miller, S. J.
J. Am. Chem. Soc. 2001, 123, 10125-10126. abstract
See also: (a) “An End to the Protection Racket” Gani, D. abstract
Nature 2001, 414, 703-705.
(b) “Efficient Route to a Key Phosphate”
Rouhi, M.
Chemical and Engineering News 2001, October 8, p. 9. abstract
(29) “Enantioselective Synthesis of a Mitosane Core Assisted by Diversity-Based Catalyst Discovery”
Papaioannou, N.; Evans, C. A.; Blank, J. T.; Miller, S. J.
Org. Lett. 2001, 3, 2879-2882. abstract
(28) “Incorporation of Peptide Isosteres into Enantioselective Peptide-Based Catalysts as Mechanistic Probes”
Vasbinder, M. M.; Jarvo, E. J.; Miller, S. J.
Angew. Chem. Int. Ed. 2001, 40, 2824-2827. abstract
(27) “Fluorescence-Based Screening of Asymmetric Acylation Catalysts Through Parallel Enantiomer Analysis. Identification of a Catalyst for Tertiary Alcohol Resolution”
Jarvo, E. R.; Evans, C. A.; Copeland, G. T.; Miller, S. J.
J. Org. Chem. 2001, 66, 5522-5527. abstract
(26) “Selection of Enantioselective Acyl Transfer Catalysts from a Pooled Peptide Library Through a Fluorescence-Based Activity Assay: An Approach to Kinetic Resolution of Secondary Alcohols of Broad Structural Scope”
Copeland, G. T.; Miller, S. J.
J. Am. Chem. Soc. 2001, 123, 6496-6502. abstract
(25) Comment: Essay on the Future of Chemistry in Chemical and Engineering News
Miller, S. J.
Chemical and Engineering News, March 26, 2001, p. 189. abstract
2000
(24) “A Polymeric and Fluorescent Gel for Combinatorial Screening of Catalysts”
Harris, R. F.; Nation, A. J.; Copeland, G. T.; Miller, S. J.
J. Am. Chem. Soc. 2000, 122, 11270-11271. abstract
(23) “Asymmetric Acylation Reactions Catalyzed by Conformationally Biased Octapeptides”
Jarvo, E. R.; Vasbinder, M. M.; Miller, S. J.
Tetrahedron 2000, 56, 9773-9779. abstract
(22) “Asymmetric Conjugate Addition of Azide to a,b-Unsaturated Carbonyl Compounds Catalyzed by Simple Peptides”
Horstmann, T. E.; Guerin, D. J.; Miller, S. J.
Angew. Chem. Int. Ed. 2000, 39, 3635-3638. abstract
(21) “A His-Pro-Aib Peptide that Exhibits an Asx-Pro Turn-Like Structure”
Blank, J. T.; Guerin, D. J.; Miller, S. J.
Org. Lett. 2000, 2, 1247-1249. abstract
1999
(20) “A Biomimetic Approach to Asymmetric Acyl Transfer Catalysis”
Jarvo, E. R.; Copeland, G. T.; Papaioannou, N.; Bonitatebus, P. J., Jr.; Miller, S. J.
J. Am. Chem. Soc. 1999, 121, 11638-11643. abstract
See also: “The Future of Synthetic Organic Chemistry”
Zurer, P.
Chemical and Engineering News 1999, September 13, pp. 31-36. abstract
(19) “Amine-Catalyzed Addition of Azide Ion to a,b-Unsaturated Carbonyl Compounds”
Guerin, D. J.; Horstmann, T. E.; Miller, S. J.
Org. Lett. 1999, 1, 1107-1109. abstract
(18) “A Chemosensor-Based Approach to Catalyst Discovery in Solution and on Solid Support”
Copeland, G. T.; Miller, S. J.
J. Am. Chem. Soc. 1999, 121, 4306-4307. abstract
See also:
(a) “News and Features” abstract
Analytical Chemistry 1999, 71, p. 438A.
(b) “Go With the Glow”
Guterman, L.
New Scientist 1999, May 22, p 14.
(c) “Bead-Bound Sensors Provide New Approach to Catalyst Discovery”
Borman, S.
Chemical and Engineering News 1999, May 17, p. 73. abstract
1998
(17) “Minimal Acylase-Like Peptides. Conformational Control Over Absolute Stereospecificity”
Copeland, G. T.; Jarvo, E. R.; Miller, S. J.
J. Org. Chem. 1998, 63, 6784-6785. abstract
(16) “Kinetic Resolution of Alcohols Catalyzed by Tripeptides Containing the N-Alkylimidazole Substructure”
Miller, S. J.; Copeland, G. T.; Papaioannou, N.; Horstmann, T. E.; Ruel, E. M.
J. Am. Chem. Soc. 1998, 120, 1629-1630. abstract
1997
(15) “Diastereoselective Enolsilane Coupling Reactions”
Miller, S. J.; Bayne, C. D.
J. Org. Chem. 1997, 62, 5680-5681. abstract
Publications as a postdoctoral fellow with Professsor Robert H. Grubbs at Caltech
(14) “Template-Promoted Dimerization of C-Allylglycine: A Convenient Synthesis of (S,S)-2,7-Diaminosuberic Acid”
O’Leary, D. J.; Miller, S. J.; Grubbs, R. H.
Tetrahedron Lett. 1998, 39, 1689-1690. abstract
(13) Patent: ”Synthesis of Conformationally Restricted Amino Acids, Peptides and Peptidomimetics by Catalytic Ring-Closing Metathesis”
Grubbs, R. H.; Miller, S. J.; Blackwell, H. E. U.S. Patent #5,811,515.
(12) “Application of Ring-Closing Metathesis to the Synthesis of Rigidified Amino Acids and Peptides”
Miller, S. J.; Blackwell, H. E.; Grubbs, R. H.
J. Am. Chem. Soc. 1996, 118, 9606-9614. abstract
(11) Review: ”Ring-Closing Metathesis and Related Processes in Organic Synthesis”
Grubbs, R. H.; Miller, S. J.; Fu, G. C.
Acc. Chem. Res. 1995, 28, 446-552. abstract
(10) “Synthesis of Conformationally Restricted Amino Acids and Peptides Using Olefin Metathesis”
Miller, S. J.; Grubbs, R. H.
J. Am. Chem. Soc. 1995, 117, 5855-5856. abstract
(9) “Catalytic Ring-Closing Metathesis (RCM) of Dienes: Application to the Synthesis of Eight-Membered Rings”
Miller, S. J.; Kim, S.-H.; Chen, Z.-R.; Grubbs, R. H.
J. Am. Chem. Soc. 1995, 117, 2108-2109. abstract
Publications as a student with Professsor David A. Evans at Harvard University
(8) “Bis(oxazoline) and Bis(oxazolinyl)pyridine Copper Complexes as Enantioselective Diels-Alder Catalysts: Reaction Scope and Applications”
Evans, D. A.; Barnes, D. M.; Johnson, J. S.; Lectka, T.; von Matt, P.; Miller, S. J.; Murry, J. A.; Shaughnessy, E. A.; Campos, K. R.
J. Am. Chem. Soc. 1999, 121, 7582-7594. abstract
(7) “Chiral Bis(oxazoline)copper(II) Complexes as Lewis Acid Catalysts for the Enantioselective Diels-Alder Reaction”
Evans, D. A.; Miller, S. J.; Lectka, T.; von Matt, P.
J. Am. Chem. Soc. 1999, 121, 7559-7573. abstract
(6) “Observation of a Remarkable Counter-ion Effect in the Cu(II)-catalyzed Diels-Alder Reaction”
Evans, D. A.; Murry, J.; von Mott, P.; Norcross, R. D.; Miller, S. J.
Angew. Chem. Int. Ed. 1995, 34, 798-800. abstract
(5) “Bis(imine)-Copper (II) Complexes as Chiral Lewis Acid Catalysts for the Diels-Alder Reaction”
Evans, D. A.; Lectka, T.; Miller, S. J.
Tetrahedron Lett. 1993, 34, 7027-7030. abstract
(4) “Bis(oxazoline)-Copper (II) Complexes as Chiral Catalysts for the Enantioselective Diels-Alder Reaction”
Evans, D. A.; Miller, S. J.; Lectka, T.
J. Am. Chem. Soc. 1993, 115, 6460-6461. abstract
(3) “Asymmetric Synthesis of the Benzoquinoid Ansamycin Antitumor Antibiotics: Total Synthesis of Macbecin”
Evans, D. A.; Miller, S. J.; Ennis, M. D.
J. Org. Chem. 1993, 58, 471-485. abstract
(2) “Asymmetric Synthesis of Macbecin I”
Evans, D. A.; Miller, S. J.; Ennis, M. D.; Ornstein, P. L.
J. Org. Chem. 1992, 57, 1067-1069. abstract
(1) “Murine Teratology and Pharmacokinetics of the Enantiomers of Sodium 2-Ethylhexanoate”
Collins, M. D.; Scott, W. J.; Miller, S. J.; Evans, D. A.; Nau, H.
Toxicol. Appl. Pharmacol. 1992, 112, 257-265. abstract